Flotation and depression control of arsenopyrite through pH and pulp redox potential using xanthate as the collector     

A. López Valdivieso  A.A. Sánchez López  C. Ojeda Escamilla  M.C. Fuerstenau 《International Journal of Mineral Processing》2006

The role of pH and pulp redox potential (E_H) to control the flotation and depression of arsenopyrite has been investigated through studies on microflotation of arsenopyrite crystals and batch flotation of an arsenopyritic ore using isopropyl xanthate as collector. The transition between flotation and depression of arsenopyrite is established by the reversible potential of the xanthate/dixanthogen couple. Adsorption of arsenate ions on ferric hydroxide has been studied through electrokinetics to delineate mechanisms involved in the depression of arsenopyrite using oxidants. Chemical binding between arsenate species and ferric hydroxide sites on arsenopyrite is suggested as the mechanism responsible for depression of arsenopyrite. E_H conditions are given for the flotation and depression of arsenopyite at various pH values for the arsenopyritic ore.  相似文献   

GIS技术支持下的招远市金矿区崩塌遥感调查     

吴泉源  姜春玲  邹敏  杨圣军  张祖陆 《山地学报》2006,24(6):672-677

在总结前人研究成果的基础上,全面系统地分析了诱发招远市金矿区崩塌的自然和人为因数,然后运用遥感技术对金矿区遥感图像进行处理,提取诱发崩塌的条件因子,聘请有经验的专家对各项诱发因子进行诊断分析,以此作为判断条件,在G IS技术的支持下对诱发崩塌的条件因子进行空间分析,预测出招远金矿区发生崩塌的危害程度,为防治崩塌提供科学依据。预测结果表明,招远金矿区崩塌有进一步发展的可能,其中,高危险区有36820 m2,中易发区有50 610 m2,低易发区有67 200 m2,需要采取有效措施加以防治。  相似文献   

Natural siliceous dust and human health： Pathways, toxicity, and impact     

Edward Derbyshire 《中国地球化学学报》2006,25(B08):219-219

Fine atmospheric dust includes mineral particles and aggregates, fibrous minerals and fibrous organic material. Generation, dislodgement and transport （deflation） of natural dust with the finer （〈4 microns） components suspended as silt-size aggregates, is widespread in and adjacent to the world＇s drylands, as well as deriving from volcanic vents. Silica is a highly fibrogenic agent in lung tissue. Long-term inhaling of siliceous dusts can lead to a number of fibrotic lung diseases, including natural （non-occupational） pneumoconioses （notably silicosis, but including asbestosis and others）. Different polymorphs of silica show different levels of toxicity in interaction with lung tissue. Particles with highly active surfaces may release radicals, causing cell damage. Some types of inhaled particulates are degraded by macrophages, but many are highly resistant and persist in the lungs, some stimulating fibroblastic cells to deposit collagen. Silicosis is an inflammation of the lung commonly caused by silicate mineral particles, leading to fibrosis. Three types are recognized： nodular pulmonary fibrosis （simple or chronic silicosis）, acute silicosis, and accelerated silicosis. Generally, finer particulates have greater oxidative capacity than the coarser fractions. They contain more reactive oxygen species, their greater bioreactivity making them more toxic to pulmonary tissue. Nevertheless, inhalation of large dust particles （〉 10μm） may constitute a health risk if the mineralogy is toxic, regardless of where the grains lodge in the respiratory system. Dust may absorb harmful gases, disease-generating bacteria and carcinogenic hydrocarbon compounds. Silica-related respiratory disease may also an exacerbate cardiac problem, and epidemiology suggests a link with tuberculosis. Quantification of dust loading and exposure requires study of spatial and temporal patterns, supported by meteorological analysis, airflow modeling and satellite-borne imagery. Some acute, short-term health impacts have been assessed using atmospheric and health records both before and after a dust storm or by comparison of populations within and outside such events. Analysis of the size, shape, mineralogy and geochemistry of ambient dust particulates provides information on natural dust sources, dust concentrations, and potential particulate toxicity, as well as providing a datum for assessment of human exposure levels.  相似文献   

Total gaseous mercury emissions from mercury-enriched soil in Guizhou, China     

Xinbin FENG Shaofeng WANG Guangle QIU Yamin HOU Shunlin TANG 《中国地球化学学报》2006,25(B08):243-244

Guizhou is located in the Circum-Pacific Global Mercuriferous Belt, and mercury concentrations in soil in this area are enriched. In-situ total gaseous mercury （TGM） exchange fluxes between air and soil surface were intensively measured at four sampling sites in Guiyang from 21 May to 16 June, 2003, and five sites in the Lanmuchang mercury mining area in December 2002 and May 2003, respectively. The in-situ Hg flux measurement was conducted with a dynamic flux chamber （DFC） of quartz. Overall, net emissions were obtained from all sampling sites. Soil mercury concentration and solar radiation have been proved to be the two most important parameters to control mercury emissions from soil. Meanwhile, rain events can enhance mercury emission rate significantly.  相似文献   

Heavy metals in freshly deposited sediments of the river Subernarekha, India: an example of lithogenic and anthropogenic effects   总被引：1，自引：0，他引：1  

A. K. Upadhyay  K. K. Gupta  J. K. Sircar  M. K. Deb  G. L. Mundhara 《Environmental Geology》2006,50(3):397-403

Heavy metal distribution patterns in river sediments aid in understanding the exogenic cycling of elements as well as in assessing the effect of anthropogenic influences. In India, the Subernarekha river flows over the Precambrian terrain of the Singhbhum craton in eastern India. The rocks are of an iron ore series and the primary rock types are schist and quartzite. One main tributary, the Kharkhai, flows through granite rocks and subsequently flows through the schist and quartzite layers. The Subernarekha flows through the East Singhbhum district, which is one of India’s industrialised areas known for ore mining, steel production, power generation, cement production and other related activities. Freshly deposited river sediments were collected upstream and downstream the industrial zone. Samples were collected from four locations and analysed in <63-μm sediment fraction for heavy metals including Zn, Pb, Cd and Cu by anodic stripping voltammetry. Enrichment of these elements over and above the local natural concentration level has been calculated and reported. Sediments of the present study are classified by Muller’s geo-accumulation index (I _geo) and vary from element to element and with climatic seasons. During pre-monsoon period the maximum I _geo value for Zn is moderately to highly polluted and for Cu and Pb is moderately polluted, respectively, based on the Muller’s standard. Anthropogenic, lithogenic or cumulative effects of both components are the main reasons for such variations in I _geo values. The basic igneous rock layer through which the river flows or a seasonal rivulet that joins with the main river may be the primary source for lithogenic components.  相似文献   

世界自然遗产事业发展潜势分析   总被引：1，自引：0，他引：1  

张忍顺  张祥国  蒋姣芳  葛云健 《地理与地理信息科学》2006,22(1):57-61

世界遗产(以下简称遗产)的申报和保护在策略、重点与工作方式上出现许多新的趋向。《凯恩斯决议》的修订突出对生态、地质演进及生物多样性价值的重视,并提高人们对自然遗产的认识水平,有助于完善自然遗产地的覆盖范围和世界遗产名录平衡性问题。这将加快自然类遗产的申报,尤其是涉及水圈的自然遗产,如海洋、淡水、山地及与此有关的生物多样性的自然遗产地的保护成为热点。国际协作使得跨国自然遗产的联合申报成为必然趋势。随着遗产保护地由点向线、面的扩展,绿色廊道遗产的建设将促进自然遗产事业的发展。  相似文献   

面向问题的空间应用表达与实现     

陈斌  黄凤茹  黄舟  彭霞  高勇  方裕 《地理与地理信息科学》2006,22(3):13-17

讨论空间应用的一种面向问题的表达方法与实现机制。为解决空间应用的描述问题,在建立时空一体化空间数据模型基础上,定义了对SQL进行扩展的时空复合查询语言,实现了对空间应用问题的非过程化描述;研究复杂空间应用的表达问题,讨论时空复合查询语言的限制,并在语言中引入流机制,通过空间应用问题的组合实现更为复杂的空间应用,并支持空间数据分布式计算;最后给出若干空间应用实例及其面向问题的表达。  相似文献   

Defending national linguistic territories in the European Single Market: towards more transnational geolinguistic analysis     

Mark Wise 《Area》2006,38(2):204-212

This paper calls for more analysis of contemporary transnational linguistic movements. Geographers have hitherto focused on linguistic problems within states and paid less attention to issues that arise as languages, notably English, are used internationally across state boundaries. It does this by examining a conflict that arose when forces integrating the supranational European Single Market space came into conflict with a Member State's determination to protect the linguistic 'integrity' of its national territory. This conflict would appear to be a precursor of similar ones to come as languages increasingly compete in a linguistic market within an integrating Europe and a globalizing world.  相似文献   

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

土壤天然热释光测量在寻找滑坡体边界中的应用研究   总被引：1，自引：1，他引：1  

张丽娇  叶树林  刘庆成 《工程地质学报》2006,14(6):815-818

土壤天然热释光测量方法是一种累积型测氡方法。由于累积测氡时间长,其灵敏度和异常的重现性远比一般累积测氡及其子体方法好,因此,在地质领域得到了广泛的应用。在寻找滑坡体边界的应用中,取得的测量效果明显,表明该方法经济有效。  相似文献